The Windows 7 taskbar explorer.exe shortcut icon, by defaults, opens the Libraries folder. We have already seen how you can make it open the Computer folder instead. In this post, I will tell you how to make it open any folder of your choice.
Right click the explorer taskbar icon and then again right-click the small explorer icon and select Properties.
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Now under the Properties Shortcut tab, in the Target box, add the path of the folder you’d like to be opened when you click on the icon, after %windir%\explorer.exe. In the image, I have used the folder path C:\Users\ACK\Downloads and set it to open my custom Downloads folder.

If you want say your C drive to be opened, simply mention C:\. Click Apply/OK, once done.
You can make it open any folder of your choice by mentioning its path after %windir%\explorer.exe. You can also make it open system folders.
Here are a few commands for some important system folders which you can use:
To open Documents folder:
%windir%\explorer.exe ::{450D8FBA-AD25-11D0-98A8-0800361B1103}
To open Network folder:
%windir%\explorer.exe ::{208D2C60-3AEA-1069-A2D7-08002B30309D}
To open Recycle Bin:
%SystemRoot%\explorer.exe /N,::{645FF040-5081-101B-9F08-00AA002F954E}
To open Computer Search Folder:
%SystemRoot%\explorer.exe ::{1F4DE370-D627-11D1-BA4F-00A0C91EEDBA}
To open Control Panel:
%SystemRoot%\explorer.exe ::{20D04FE0-3AEA-1069-A2D8-08002B30309D}\::{21EC2020-3AEA-1069-A2DD-08002B30309D}
Hope it works for you!
